基于嫦娥二号微波辐射计数据月球中低纬度亮温异常区地质分析研究   总被引：1，自引：0，他引：1  

连懿  陈圣波  孟治国  张莹  路鹏 《地球学报》2014,35(5):643-647

月球表面的微波辐射亮度温度与月表地质结构和月表物质的物理化学特性相关。为了对月球亮温分布异常区域进行地质分析,文章首先计算嫦娥亮温数据的时角,采用克里金插值的方法得到了不同频率不同时刻中低纬度的微波亮温图。结合奇异值分解(SVD)模型分析了月表亮温变化异常,结果表明风暴洋位置和靠近月海东北部的高地区域等存在亮温变化异常,月海区域(除风暴洋外)为3 GHz和37 GHz两个场的总体相关区域。通过对月球火山分布地区的区域亮温变化进行分析,发现这热异常可能是由于月球火山活动造成的。  相似文献   

Sulfur Concentration in Geochemical Reference Materials by Solution Inductively Coupled Plasma‐Mass Spectrometry     

Monica E. Erdman  Cin‐Ty A. Lee  Wenbo Yang  Lynn Ingram 《Geostandards and Geoanalytical Research》2014,38(1):51-60

With implications for the origin of ore deposits, redox state of the atmosphere, and effects of volcanic outgassing, understanding the sulfur cycle is vital to our investigation of Earth processes. However, the paucity of sulfur concentration measurements in silicate rocks and the lack of well‐calibrated reference materials with concentrations relevant to the rocks of interest have hindered such investigations. To aid in this endeavour, this study details a new method to determine sulfur concentration via high mass resolution solution inductively coupled plasma‐mass spectrometry (ICP‐MS). The method is based on an aqua regia leach, involving relatively rapid sample preparation and analysis, and uses small test portion masses (< 50 mg). We utilised two independently prepared standard solutions to calibrate the analyses, resulting in 4% accuracy, and applied the method to eight geochemical reference materials. Measurements were reproducible to within ~ 10%. Sulfur concentrations and isotopes of six reference materials were measured additionally by elemental analyser‐combustion‐isotope ratio mass spectrometry to independently evaluate the accuracy of the ICP‐MS method. Reference materials that yielded reproducible measurements identical to published values from other laboratories (JGb‐1, JGb‐2 and MAG‐1) are considered useful materials for the measurement of sulfur. Reference materials that varied between studies but were reproducible for a given test portion perhaps suffer from sample heterogeneity and are not recommended as sulfur reference materials.  相似文献   

敞开酸溶-电感耦合等离子体质谱法同时测定钨矿石和锡矿石中14种微量元素   总被引：4，自引：4，他引：0       下载免费PDF全文

杨小莉  杨小丽  李小丹  邵鑫  杨梅 《岩矿测试》2014,33(3):321-326

钨矿石和锡矿石成分复杂,具有丰富的共生或伴生元素。在国家标准方法中,对其中的微量共生或伴生元素含量多采用单元素测定,分析强度大,效率低。本文采用混合酸在敞开体系中消解样品,以50%盐酸提取盐类,电感耦合等离子体质谱仪(ICP-MS)同时测定钨矿石和锡矿石中的锂钪铬钴镍铜铅锌铷钼铯锑铋钍等14种微量元素。通过比较碱熔法、盐酸+氢氟酸+硝酸+高氯酸四酸溶矿法、氢氟酸+硝酸+高氯酸三酸溶矿法这三种样品前处理方法,确定选择使用氢氟酸+硝酸+高氯酸三酸溶矿法溶解样品。ICPMS测定过程中,选择铑和铼作为内标元素,有效监控分析信号的漂移。测定结果表明,各元素的检出限为0.003~1.64μg/g,相对标准偏差在0.1%~3.1%,方法回收率在93.1%~104.3%。方法应用于实际钨矿石和锡矿石分析,测定结果与各元素标准测定值吻合较好。相对于传统处理方法,本法一次溶样,多元素同时测定,使分析效率得到了有效提高,更适合大批量多元素钨矿石和锡矿石样品的分析。  相似文献   

微波消解-电感耦合等离子体质谱测定铜精矿中7种稀有金属元素   总被引：1，自引：1，他引：0       下载免费PDF全文

燕娜  赵生国  赵伟  郑红文 《岩矿测试》2014,33(2):197-202

准确快速测定铜精矿中7种稀有金属元素（镓铟锗硒碲铊镧）的分布情况对于铜精矿的综合利用及减少技术性贸易壁垒等方面具有重要意义,因锗和铊等目标元素含量低至10^-7级,要求分析方法具有高灵敏度。本文应用微波消解-电感耦合等离子体质谱方法实现了7种稀有金属元素的快速准确测定。以盐酸-硝酸混合酸（体积比3：2）作为样品的微波消解试剂,选取合适的分析质量、调谐仪器及数学校正方程等三种方式消除质谱干扰。在优化的实验条件下,目标元素加标回收率为80.2%~123.3%,相对标准偏差小于13.4%。硒的检出限为1.3 mg/kg,另外6种目标元素的检出限均低于0.08 mg/kg。本法目标元素的检出限均低于电感耦合等离子体发射光谱或原子吸收光谱法测定相应元素的检出限。该方法降低了试剂空白,简化了操作流程,提高了分析灵敏度,实现了铜精矿目标元素的同时分析。  相似文献   

应用响应曲面法优化凯氏定氮法的消解条件   总被引：1，自引：1，他引：0       下载免费PDF全文

杨娜  董迈青  谢海东  邢谦 《岩矿测试》2014,33(1):40-43

经典凯氏定氮法是通过观察消解反应现象来控制温度和时间,对于数量较多的样品同时消解会耗费大量的人力及时间,因此需要采用合理的试验设计方法确定最佳消解温度和时间,以实现批量消解样品,提高分析效率。本文利用响应曲面法对凯氏定氮法中的消解条件进行了优化分析,选择料液比、消解温度和消解时间作为优化因素,研究三因素的不同水平对氮含量测定的影响。通过响应曲面分析得到最优的消解条件为:料液比(g/mL)=0.3∶5,消解温度260℃,消解时间60 min。重复实验结果表明,样品在优化的条件下能够很好地消解,重现性较好;标准物质的氮含量的实验测定值(1310×10-6)与标准值(1300×10-6)基本一致,两者的对数误差绝对值为0.003,方法的准确性高。应用响应曲面试验设计方法,对于评价凯氏定氮法中三个消解条件对氮含量的非线性影响起到了很好的优选作用,能更好地预测实验因素对分析结果的影响趋势,可以准确控制消解温度和消解时间,对于提高分析效率具有实用意义。  相似文献   

微波等离子体炬质谱技术快速鉴别天然石材与人造石材   总被引：1，自引：1，他引：0  

周炜  熊海龙  杨美玲  陈焕文  屈颖  张兴磊  方小伟 《岩矿测试》2014,33(6):782-788

天然石材主要有大理石、花岗岩等;人造石材多以不饱和聚酯树脂为基料,添加适量的无机物粉料和添加剂固化制成。由于石材种类繁多,并且各种石材的岩体所含矿物成分也有差异,当前很少应用化学成分分析方法准确、快速鉴别天然和人造石材,仅有的红外光谱法由于对待测物纯度的要求较高而具局限性。本文基于微波等离子体炬源(MPT)同时具有热解吸与强电离能力,能在短时间内离子化待测物的特点,采用微波等离子体炬质谱(MPT-MS)技术,无需样品复杂预处理直接对天然与人造石材进行分析,获得正离子检测模式下在m/z 50~1000之间的石材的指纹谱图,并运用化学计量学的主成分分析(PCA)方法处理所获取的数据,实现了不同建筑石材的区分。结果表明,MPT-MS能够获得石材丰富的指纹谱图,结合PCA方法能够快速鉴别天然石材与人造石材,天然石材中解吸出的物质主要为CO₂和H₂O的团簇分子;而人造石材中解吸出的主要成分为有机物(人为添加的黏合剂等)。本研究采用的MPT-MS技术无需采用喷雾、激光、基质和加热等方法辅助,并且无需对石材进行任何复杂的处理即可进行质谱分析,从而获取石材表面及内部物质的质谱信息,为快速直接鉴定石材样品提供了一种新的质谱分析方法。  相似文献   

Mysteries on universe’s largest observable scales     

Dragan Huterer   《New Astronomy Reviews》2006,50(11-12):868

We review recent findings that the universe on its largest scales shows hints of violations of statistical isotropy, in particular alignment with the geometry and direction of motion of the solar system, and missing power at scales greater than 60°. We present the evidence, attempts to explain it using astrophysical, cosmological or instrumental mechanisms, and prospects for future understanding.  相似文献   

No Higher Criticism of the Bianchi-corrected Wilkinson Microwave Anisotropy Probe data     

L. Cayón  A. J. Banday  T. Jaffe  H. K. Eriksen  F. K. Hansen  K. M. Gorski  J. Jin 《Monthly notices of the Royal Astronomical Society》2006,369(2):598-602

Higher Criticism (HC) has been proposed by Donoho & Jin as an effective statistic to detect deviations from Gaussianity. Motivated by the success of the Bianchi VII_h model in addressing many of the anomalies observed in the Wilkinson Microwave Anisotropy Probe ( WMAP ) data (Jaffe et al.), we present calculations in real and in wavelet space of the HC statistic of the Bianchi-corrected WMAP first-year data. At the wavelet scale of 5°, the HC of the WMAP map drops from a value above the 99 per cent confidence level (c.l.) to a value below the 68 per cent CL when corrected by the Bianchi template. An important property of the HC statistic is its ability to locate the pixels that account for the deviation from Gaussianity. The analysis of the uncorrected WMAP data pointed to a cold spot in the Southern hemisphere, centred at   l ∼ 209°, b ∼−57°  . The HC of the Bianchi-corrected map indicates that this spot remains prominent, albeit at a level completely consistent with Gaussian statistics. Consequently, it is debatable how much emphasis should be placed on this residual feature, but we consider the effect of modestly increasing the scaling of the template. A factor of only 1.2 renders the spot indistinguishable from the background level, with no noticeable impact on the results published in Jaffe et al. for the low- l anomalies, large-scale power asymmetry or wavelet kurtosis. A trivial interpretation would be that the Bianchi template may require a small enhancement of power on scales corresponding to the wavelet scale of 5°.  相似文献   

Seasonal inundation patterns in two large savanna floodplains of South America: the Llanos de Moxos (Bolivia) and the Llanos del Orinoco (Venezuela and Colombia)     

Stephen K. Hamilton  Suzanne J. Sippel  John M. Melack 《水文研究》2004,18(11):2103-2116

Inundation patterns in two of the largest savanna floodplains of South America were studied by analysis of the 37‐GHz polarization difference observed by the Scanning Multichannel Microwave Radiometer (Nimbus‐7 satellite). Flooded area was estimated at monthly intervals for January 1979 through to August 1987 using mixing models that account for the major landscape units with distinctive microwave emission characteristics. Results are presented separately for five subregions in each of the two floodplain regions to show the spatial as well as temporal variability in inundation patterns. The total area inundated during the 9 years varied between 2069 and 78 460 km² in the Llanos de Moxos (also spelled as Mojos; median area, 23 383 km²) and 1278 and 105 454 km² in the Llanos del Orinoco (median, 25 374 km²), not including the open‐water area of permanent lakes and river channels. The correlation between flooded area and river stage was used to extend the inundation records over a 30‐year period in the Moxos (1967–97) and a 58‐year period (1927–85) in the Orinoco. Interannual variability in inundation is greater in the Moxos than the Orinoco. Comparison of these data, however, with a previously published analysis of the Pantanal wetland shows that inundation patterns in these two floodplain regions are not as variable across years as they are in the Pantanal. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

Precision era of the kinetic Sunyaev–Zel'dovich effect: simulations, analytical models and observations and the power to constrain reionization     

Pengjie Zhang  Ue-Li Pen  Hy Trac 《Monthly notices of the Royal Astronomical Society》2004,347(4):1224-1233

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